Organische Leiter

Only three decades ago it was thought inconceivable that organic compounds could transport electric charges like metals do. However, recently organic molecules exhibiting high conductivities have been synthesized. Some examples of organic conductors are presented together with the present status of this research which is both interesting to chemists and physicists. Some applications of organic conductors are discussed.     

Impact of Land Use on Soluble Organic Nitrogen in Soil

Although it has been hypothesized that soluble organic nitrogen (SON) plays a central role in regulating productivity in some terrestrial ecosystems, the factors controlling the size of the SON pool in soil remain poorly understood. Therefore our principal aim in this work was to assess the impact of seven different land use systems (rough and managed grassland, deciduous and coniferous woodland, heathland, wetland and tilled land) on the size of the SON and inorganic N (NO ₃ ^– , NH ₄ ⁺ ) pools in the surface soil layer (0–15 cm). After extraction with deionised water, we found that in most cases the size of the water extractable organic N (WEON) pool was similar in size to the inorganic N pool. In contrast, the KCl extractable organic N (KClEON) pool constituted the dominant form of soluble N in soils under all land uses, perhaps indicating that significant amounts were held on the soil exchange phase. In contrast to inorganic N, which varied significantly with land use, the size of the KClEON and WEON pool was similar for all land uses with the exception of KClEON in tilled land, where significantly lower amounts were observed. We conclude that SON constitutes an important soil N pool in a broad range of land uses, and that its role in microbial N assimilation, plant nutrition and ecosystem responses to atmospheric N deposition warrants further attention. SAFRD, University of Newcastle, Newcastle-upon-Tyne, NE1 7RU, U.K.     

Assessing the ecological effects of human impacts on coral reefs in Bocas del Toro,Panama

Environmental and biological reef monitoring was conducted in Almirante Bay (Bahía Almirante) in Bocas del Toro, Panama, to assess impacts from anthropogenic developments. An integrated monitoring investigated how seasonal temperature stress, turbidity, eutrophication and physical impacts threatened reef health and biodiversity throughout the region. Environmental parameters such as total suspended solids [TSS], carbon isotopes (δ¹³C), C/N ratios, chlorophyll a, irradiance, secchi depth, size fractions of the sediments and isotope composition of dissolved inorganic carbon [DIC] of the water were measured throughout the years 2010 and 2011 and were analysed in order to identify different impact sources. Compared to data from Collin et al. (Smithsonian Contributions to the Marine Sciences 38:324–334, 2009) chlorophyll a has doubled at sites close to the city and the port Almirante (from 0.46–0.49 to 0.78–0.97 μg l^?1) and suspension load increased, visible by a decrease in secchi depth values. Visibility decreased from 9-13 m down to 4 m at the bay inlet Boca del Drago, which is strongly exposed to river run off and dredging for the shipping traffic. Eutrophication and turbidity levels seemed to be the determining factor for the loss of hard coral diversity, most significant at chlorophyll a levels higher than 0.5 μg l^?1 and TSS levels higher than 4.7 mg l^?1. Hard coral cover within the bay has also declined, at some sites down to <10 % with extremely low diversities (7 hard coral species). The hard coral species Porites furcata dominated the reefs in highly impacted areas and showed a strong recovery after bleaching and a higher tolerance to turbidity and eutrophication compared to other hard coral species in the bay. Serious overfishing was detected in the region by a lack of adult and carnivorous fish species, such as grunts, snappers and groupers. Study sites less impacted by anthropogenic activities and/or those with local protection showed a higher hard coral cover and fish abundance; however, an overall loss of hard coral diversity was observed.     

Seeing the forest not for the carbon: why concentrating on land-use-induced carbon stock changes of soils in Brazil can be climate-unfriendly

Regional Environmental Change - Soil carbon stocks of 29 plots along a transect through tropical Brazil showed only minor soil carbon losses after land use shift, although replacement of...     

A Cyclone for Size-Selective Sampling of Ambient Air

A cyclone with a 47 mm after-filter has been developed for ambient air size-selective monitoring. It has been extensively evaluated with laboratory-generated aerosol. Variation of the pressure drop and 50% cut point with flow rate show that the cyclone operates in a single flow regime with a vortex in the outlet flow. The particle size cutoff curve is comparable in sharpness to a cascade impactor and is the same for solid or liquid particles. At 21.7 L/min, D ₅₀ is 2.5μm and at 15.4 L/min, D ₅₀ is 3.5 μm. Collection efficiency data for flow rates from 8 to 27 L/min fit a universal curve when plotted vs. the normalized particle diameter, (D-D ₅₀)/D ₅₀ Reentrainment of previously deposited particles is less than 1 % of the loading per day. In field tests the cyclone has proved to be a very satisfactory size-selective sampler.